FINDING THE ELUSIVE IODOCARBENE: FLUORESCENCE EXCITATION AND SINGLE VIBRONIC LEVEL EMISSION SPECTROSCOPY OF CHI
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Abstract
Among the triatomic halocarbenes, only the iodocarbenes remain to be characterized. The search for these elusive species is motivated by a controversy regarding the multiplicity of the ground state. Photoelectron spectra of Lineberger and co-workers suggest a triplet ground state for CHI, at variance with recent
Description
M.~K.~Gilles, K.~M.~Ervin, J.~Ho, and W.~C.~Lineberger, J.~Phys.~Chem. 96, 1130 (1992).
Author Institution: Department of Chemistry, Marquette University, Milwaukee, WI 53233; Department of Chemistry, Brookhaven National Laboratory, Upton, NY 11973