EXCITON BAND OF A ONE MOLECULE-PER-CELL CRYSTAL: HEXAMETHYLBENZENE

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1972

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Ohio State University

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Abstract

Two methods for the determination of exciton structure are employed for this system (which cannot exhibit a Davydov splitting): The band-to-band (“hot band”) transition method1, and the heavily doped isotopic mixed crystal method. The experiments involve single crystals at low temperature (1.5K ) and medium high resolution (0.5cm−1). Results will be discussed in terms of translationally equivalent exciton interactions and effective one-dimensional energy transfer.

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1 S.D. Colson, D.M. Hanson, R. Kopelman and G. W. Robinson, J. Chem. Phys. 48, 2215 (1968).""


Author Institution: Department of Chemistry, University of Michigan

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