HIGH RESOLUTION ELECTRONIC SPECTRUM OF THE PARA-DIFLUOROBENZENE/WATER $COMPLEX^{a}$

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2000

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Ohio State University

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The rotationally resolved S1←S0 fluorescence excitation spectrum of para-difluorobenzene (pDFB)/water complex has been observed. The water complex appears 169cm−1 to the blue of the bare molecule origin and is split into two spectra separated by 0.12cm−1. These spectra are a result of the internal rotation of the water molecule in the complex. Analyses of the bands show that the water molecule lies in the ab plane of the pDFB molecule. The possible types of water motion will be discussed.

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awork supported by NSF


Author Institution: Department of Chemistry, University of Pittsburgh

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http://hdl.handle.net/1811/19728

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Abstracts of OSU International Symposium on Molecular Spectroscopy 2000-2009