MAGNETIC CIRCULAR DICHROISM SPECTRA OF HEMIN IN VARIOUS ENVIRONMENTS

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1968

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Ohio State University

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The MCD spectra of hemin complexed with some nitrogen-containing ligands have been obtained, and some of the absorption bands have been tentatively assigned as a result. Included in the series of ligands are pyridine, ammonia, some trisbstituted amines, and cyanide. The oxidation state and spin configuration of the iron atom have been determined by electron paramagnetic resonance for each complex.

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Author Institution: Department of Physics, Texas A&M University; Department of Chemistry, Texas A&M University; Department of Chemistry, Southwest Research Institute

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