PERTURBATIONS IN THE B STATE OF $S_{2}$
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Date
1985
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Publisher
Ohio State University
Abstract
Though the B - X system of $S_{2}$ has been studied by many people, the upper $B^{3}\Sigma^{-}_{u}$ state, being highly perturbed, still presents a few anomalies. Line intensities and line position anomalies in high resolution CW laser absorption measurements of the [8,1] band of the $B - X$ system are explained in terms of $B^{3}\Sigma^{-}_{u} - {B^{\prime\prime}}^{3}\Pi_{u}$ perturbations, using recent results of Matsumi et $al.^{1}$ Approaches to deriving deperturbed constants for the B and $B^{\prime\prime}$ states of of $S_{2}$ will be discussed.
Description
$^{1}$Y. Matsumi, T. Munakata, and T. Kasuya, J. Chem. Phys. 81, 1108, (1984).
Author Institution: Department of Chemistry, Drerel University; Department of Chemistry, Drerel University
Author Institution: Department of Chemistry, Drerel University; Department of Chemistry, Drerel University