HIGH RESOLUTION SPECTROSCOPY OF BENZYL AND RELATED RADICALS

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1991

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Ohio State University

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Rotationally resolved LIF electronic spectra of jet cooled benzyl radical have been recorded for the type-A $A^{1}$ and type-B $6a^{1}_{0}$ bands. Calibrated band frequencies, ground state and excited state rotational constants have been well determined. Results confirm and extend earlier contour analysis of spectra obtained with absorption $techniques.^{1}$ Recent results from other aryl-substituted radicals will also be presented.

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$^{1}$ C. Cossart-Magos and W. Goetz, J. of Mol. Spec. 115, 366 (1986).""
Author Institution: Department of Chemistry, The Ohio State University, Laser Spectroscopy Facility

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