LINESHAPE PARAMETERS OF THE OXYGEN A-BAND USING FREQUENCY-STABILIZED CAVITY RING-DOWN SPECTROSCOPY

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2007

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Ohio State University

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Laboratory spectra of the oxygen $A$-band ($b$$^{1}\Sigma ^{+}_{g} \leftarrow X^{3}\Sigma ^{-}_{g}$) have been recorded using frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) in the 12,900-13,080 cm$^{-1}$ spectral region (20$<$$N$$^{\prime \prime}$$<$40). High-resolution and high-sensitivity measurements of line shape parameters (intensities, pressure broadening and shifting) are reported. Implication of line-mixing and collision-induced absorption to far-wing absorption will be discussed.

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Author Institution: Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena CA 91125; National Institute of Standards and Technology, Gaithersburg, MD 20899; Nicolaus Copernicus University, Torun, Poland; Jet Propulsion Laboratory, Pasadena, CA 91109

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