MOLECULAR BEAM ELECTRIC RESONANCE SPECTRUM OF HF DIMER
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Date
1971
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Publisher
Ohio State University
Abstract
Using an expansion nozzle source, beams of ArXe, XeHCl, $(HCl)_{2}$ and a series of HF polymers have been observed. XeHCl, $(HCl)_{2}$ and $(HF)_{2}$ have dipole moments large enough to give refocussing in a quadrupole electrostatic field. Microwave and radiofrequency resonances have been observed for $(HF)_{2}$ and $(DF)_{2}$. The spectrum does not fit rigid rotor models. This talk will be a progress report on the spectral assignment of these species.
Description
Author Institution: Department of Chemistry, Harvard University