Electronic Spectorscoply of $CF_{3}O$ in a Supersonic Jet

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1994-MG-06.jpg (94.87 KB)

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1994

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Ohio State University

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The jet-cooled LIF spectrum of the CF3OA~←X¯ electronic transition has been observed. Rotational analysis of the high resolution spectrum of the origin band suggests that CF3O has nominal C3v symmetry in both its ground and first excited state. Vibrational analysis of the dispersed fluorescence spectrum indicates that the Jahn-Teller effect is considerably stronger in CF3O compared to CH3O. The details of analysis will be presented.

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Author Institution: Laser Spectroscoy Facility, Department of Chemistry, The Ohio State University; Department of Chemistry, University of Michigan, ; Department of Chemistry, H. L. Hunter Chemistry Laboratory , Clemson University

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http://hdl.handle.net/1811/13079

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999