THE MOLECULAR STRUCTURE OF THE $HCO^{+}$ ION BY MICROWAVE SPECTROSCOPY

Loading...
Thumbnail Image

Date

1976

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

We have confirmed the identity of the interstellar ""X-ogen"" line as the$ J = 0 {\rightarrow} 1$ transition of HCO+ by observing it in a laboratory dc glow discharge in a hydrogen-carbon monoxide mixture at liquid nitrogen temperature. Source modulation and computer controlled signal averaging were employed. The frequency is in excellent agreement with the best astrophysical determinations. We have also seen the spectra of the Hl3CO+and HC18O+ species using enriched carbon monoxide and have obtained the molecular structure from these data. Work on further isotopic forms is in progress as are efforts to obtain the pressure broadening linewidth of HCO+ due to H2 pressure.

Description

1E. F. Sheka and I. P. Terenetskaya, Chem. Phys. 8, 99 (1975).


Author Institution: Department of Chemistry, University of Wisconsin

Keywords

Citation