$A_{g7}$ CLUSTER: PENTAGONAL BIPYRAMID

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1987-TD-05.jpg (88.71 KB)

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1987

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Ohio State University

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The analysis of a well-resolved electron-spin-resonance (ESR) spectrum of a silver cluster trapped in solid neon at 4∘K has established it as Ag7. 109Ag hyperfine structure shows that the single electron spin is interacting strongly with two equivalent (axial) Ag nuclei and weakly with five equivalent (equatorial) Ag nuclei. It has D5h symmetry and a 2A2− ground state. These properties are analogous to its Group IA alkali-metal counterparts.

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Author Institution: Department of Chemistry, University of Florida; Department of Chemistry, City University of New York

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http://hdl.handle.net/1811/17337

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989