HIGH RESOLUTION SPECTRUM OF THE 1.2-DIMETHOXYBENZENE/$D_{2} O$ $COMPLEX^{a}$
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Date
2000
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Ohio State University
Abstract
The rotationally resolved $S_{1} \leftarrow S_{0}$ electronic spectrum of the 1,2-dimethoxybenzene/$D_{2}O$ complex has been analyzed. The $D_{2}O$ complex appears $126 cm^{-1}$ to the blue of the bare molecule origin. The complex spectrum exhibits two subbands separated by 45 MHz. These spectra have an intensity ratio of 2 to 1, with the stronger band shifted to lower frequency. Possible motions of the water molecule that are suggested by these data will be discussed.
Description
$^{a}$work supported by NSF
Author Institution: Department of Chemistry, University of Pittsburgh
Author Institution: Department of Chemistry, University of Pittsburgh