THE ELECTRONIC SPECTRA OF TETRAHALOFERRATE(III) COMPLEXES

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Date

1970

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Ohio State University

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Abstract

The polarized single crystal spectra of a number of alkylammonium salts of the series $FeCl_{n} Br^{-}_{4-2n}$ where n = 1 to 4, have been determined at liquid nitrogen temperatures. Complete crystal field-spin orbit calculations have been performed to aid in the spectral assignment. Evidence for a dynamic Jahn-Teller distortion in two of the excited states has been observed and will be discussed.

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Author Institution: Department of Chemistry, University of Florida; Department of Chemistry, Caisius College

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