HIGH RESOLUTION INFRARED SPECTRUM OF THE $\nu_{1}$ BAND OF $NO_{2}$

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1977

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Ohio State University

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The totally symmetric ν1, B-type band, of NO2 at 1319.794cm−1 has been studied with high resolution. This very weak vibration-rotation band exhibits very strong intensity anomalies, even stronger than those previously observed in 2ν1 and 2ν3. The P side is completely missing. The R side of the band has been clearly observed only for values of K > 3. The RPK series are the strongest; the RQK series and the RRK series which are normally stronger than the RPK series are much weaker. Spin splitting is large. The spectroscopic constants will be reported.

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Author Institution: Department of Chemistry, Universit'{e} de Sherbrooke

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http://hdl.handle.net/1811/10209

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979