ABSOLUTE ABSORPTION OF OZONE IN THE MID-INFRARED

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1992

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Ohio State University

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A number of spectroscopic investigators have measured ozone absolute intensities in different spectral regions. The mid-infrared frequencies have been studied by two techniques1,2. We report here the results of a distinctly different determination of the absorption cross section using a Bruker HR 120 Fourier transform spectrometer in the mid-infrared region. In this study, the infrared and ultraviolet, absorption of ozone were measured simultaneously using selected infrared lines of the ν3 band and the ultraviolet 253.7 nm Hg line. The accuracy of our absolute infrared intensity measurements are comparable to the 1 % spread in the ultraviolet absorption measurements at 253.7 nm3.

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1 C. Secroun, A. Barbe, P. Jouve, P. Arcas, and E. Arie, J. Mol Spectrosc. {\bf 85} , 8--15 (1981). 2 J. M. Hoell, JR., C. N. Harward, C. H. Blair, and B. S. Williams, Opt. Eng. {\bf 21} , 548--552 (1982). 3 L. T. Molina and M. J. Molina, J. Geophys. Res. {\bf 91} , 14501--14508 (1986).


Author Institution: Jet Propulsion Laboratory, California Institute of Technology

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