HIGH-SENSITIVE SUB-MILLIMETER WAVE SPECTROSCOPY OF IONS AND FREE RADICALS

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1997

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Ohio State University

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Sub-millimeter wave spectroscopy in the frequency range of over 500 GHz has not been a territory of easy access. A number of space sub-millimeter wave telescopes are launched or planned, and in view of imminent collaboration between astronomy and laboratory spectroscopy, a sub-millimeter wave spectrometer system has been constructed with Russian made BWOs as radiation sources. Frequency ranges of 570-700 GHz and 770-840 are covered with two BWOs. The sub-millimeter wave frequency is phase-locked to harmonics of a millimeter wave radiation generated by a Gunn oscillator. The sub-millimeter wave harmonic mixer was fabricated in K""{o}ln, a similar one used in G. Winnewisser’s group.m Unstable molecular species are generated either in an extended negative glow discharge cell or a hollow cathode discharge cell which can be cooled down to −80C. Several stable and unstable molecules such as 12C18O,O2(1Δg),HN2+ and their isotopes are used for assessing the sensitivity of the system. The sensitivity of our system is found to be about 2×10−7 with 1 sec time constant and with 1.5 m path length. It corresponds to minimum detectable absorption coefficient of 1.3×10−9cm−1.

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mSee, for example, S. P. Below, F. Lewen, Th. Klaus, and G. Winnewisser, J. Mol. Spectrosc. 174, 606 (1995).


Author Institution: Institute for Astrophysics and Planetary Sciences, Ibaraki University

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