AN EXAMINATION OF THE RESONANT MULTIPHOTON IONIZATION OF $CF_{3}I$

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1992

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Ohio State University

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Resonant (2+1) multiphoton ionization (MPI) has been observed in the 300--306 nm excitation region for both cold molecular beam and room temperature samples of CF3I. Excitation spectra with mass-selected ion detection will be presented and discussed. MPI/photoelectron spectra of CF3I will be used to demonstrate that parent CF3I+ ions are produced predominantely in their ground X~2E1/2 state. Tentative spectral assignments based on the photoion and photoelectron data have been made.

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Author Institution: Department of Chemistry, University of Cincinnati; Department of Chemistry, University of Kentucky

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http://hdl.handle.net/1811/12867

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999