HIGH RESOLUTION INFRARED SPECTRUM OF $CH_{3}D$
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Date
1964
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
A number of previously unreported infrared bands of $CH_{3}D$ have been observed with high resolution and have been analyzed to obtain the spectroscopic constants. The previously reported bands of $CH_{3}D$ at $2780 cm^{-1}$ and $3016 cm^{-1}$ have also been observed with better resolution than heretofore. A short discussion of the features of some of these bands will be presented. As examples of these features, it has been observed that the l-type doubling q's for the two degenerate bending modes $\nu_{5}$ and $\nu_{6}$ are of opposite sign, and the parallel component of the combination of these two modes is affected by vibrational l-type $resonance^{1,2}$.
Description
$^{1}$ Gilbert Amat and Harald H. Nielsen, J. Mol. Spectroscopy 2, 152 (1958). $^{2}$ Jon T. Hougen, J. Chem. Phys. 38, 1167 (1962).
Author Institution: National Bureau of Standards
Author Institution: National Bureau of Standards