MODELING THE TORSION-STRETCH COUPLING IN THE OH SPECTRUM OF cis-cis HOONO USING A THREE DIMENSIONAL POTENTIAL SURFACE
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\maketitle The lowest energy conformer of HOONO, the \textit{cis-cis} isomer, forms a ring structure with an internal hydrogen bond. Because of this hydrogen bond, the OH stretch frequency and band intensity are dependent on the dihedral angles HOON and OONO. The torsional motions about these angles have comparable frequencies and are coupled. Previous calculations used two dimensional models that explicitly treated the OH stretch and the HOON torsion (rotation of the OH out of the ring plane)} \textbf{122}, 104311 (2005).}
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Author Institution: Arthur Amos Noyes Laboratory for Chemical Physics, California Institute; of Technology, Pasadena, CA 91125; Department of Chemistry, The Ohio State University, Columbus, OH 43210; Arthur Amos Noyes Laboratory for Chemical Physics, California Institute; of Technology, Pasadena, CA 91125