LOW RESOLUTION MICROWAVE SPECTROSCOPY: A NEW BAND TYPE

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1975

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Ohio State University

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Abstract

We have observed a new type of band series. The lines in these bands have been used previously for high resolution assignment purposes.1,2 The approximate frequency of one of the bands is given by the following equation: \nu\sim 2{C}({J}+\frac{1}{2})+\frac{1}{2}({A}+{B}). This new series has a spacing of approximately 2C and has the property that the frequency of a band center divided by the spacing is close to J + 1/2 + (A + B)/4C. This latter quantity is in general neither integral nor half-integral. In low resolution work it is normally observed to be one or the other. A discussion of these and other characteristics of this new band type and the information that can be obtained from it will be presented.

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1 R. F. Curl, JR., T. Ikeda, and R, Kewley, J. Mol. Spectrosc. 44, 459 (1972). 2 H. M. Pickett, J. Am. Chem. Soc. 95, 1770 (1973).""


Author Institution: Mallinckrodt Chemical Laboratories, Harvard University

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