RESONANCE RAMAN EFFECT IN SOLUTIONS

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1971

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Ohio State University

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The experimental observation of the resonance Raman effect in solutions is restricted by the absorption of the sample. Under ordinary circumstances one is required to compromise between absorption and emission of the scattered light. Using a rotating Raman cell we were able to reduce the diffuseness of the incident beam due to the thermal lense effect and increase the observed Raman intensity by a factor of about ten. The Resonance Raman spectra of some highly coloured inorganic compounds (e.g. KMnO4, l2) in dilute solutions are reported. The spectra were excited with the blue and green lines of an argon ion laser. In the case of the potassium permanganate solutions seven overtones of the ν1 (A1) mode of the MnO4 ion (T4 symmetry) were observed as well as some combination tones nν1 (A1)+ν2 (F2). From the wavenumbers of the overtones of ν1 the dissociation energy of the MnO4 ion has been estimated. Overtone sequences of the I2 vibration up to the 15th harmonic were recorded and compared with the results of the Resonance Raman spectra of I2 in the gas phase.

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Author Institution: Division of Chemistry, National Research Council of Canada

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