NEW FLUORESCENCE BAND SYSTEMS OF THE DIATOMIC MOLECULES BiS, BiSe AND BiTe

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1981

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Ohio State University

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The series of diatomic molecules BiS, BiSe and BiTe, with both natural and enriched isotopic abundances, have been examined in solid inert gas matrices. Laser irradiation of the matrices produced in each case fluorescence band systems which have not previously been observed in the gas spectra of these molecules. A total of 9 new systems appeared with their origins at approximately the following frequencies: BiS, 21200, 20650 and $18400 cm^{-1}$; BiSe, 19950, 17000, and $13240 cm^{-1}$; BiTe, 18725, and $18025 cm^{-1}$. These spectra will be discussed.

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