TEMPERATURE DEPENDENCE OF NEAR RESONANT VIBRATIONAL ENERGY TRANSFERS IN $N_{2}O$ ISOTOPIC MIXTURES
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Date
1973
Journal Title
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Volume Title
Publisher
Ohio State University
Abstract
The rate constants for near-resonant energy transfer from $^{14}N_{2} ^{16}O(001)$ to $^{15}N_{2} ^{16}O, ^{14}N- ^{15}N- ^{16}O, ^{15}N- ^{14}N- {16}O, ^{13}C^{16}O_{2}$ and $^{15}N_{2}$ have been measured as a function of the temperature between 300 and $800^{\circ} K$ . Very closely resonant transfers are obtained with such isotopic species. The experimental results are compared with rate constants calculated by a theory involving long-range intermolecular forces.
Description
Author Institution: Laboratoire de Spectronomic Moleculaire, Universit\'e de Paris VI