PHOTOLYSIS OF PEROXYACETYL NITRATE (PAN) STUDIED BY CAVITY RING-DOWN SPECTROSCOPY
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Date
2003
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Publisher
Ohio State University
Abstract
Peroxyacetyl nitrate, commonly called PAN, is an important reservoir of nitrogen oxides. Peroxyacetyl nitrate is formed by reaction of partially oxidized hydrocarbons (oxidized to the peroxyacetyl radical) with $NO_{2}$. This reaction is reversible, thus PAN can be a source of $NO_{2}$ to regions remote from pollution sources. The strong temperature dependence of the PAN dissociation reaction makes PAN stable with respect to thermal decomposition at low temperatures. The lifetime with respect to thermal dissociation is 1 month at $-10^{\circ}C$ and 1 year at $-25^{\circ}C$. Therefore, other losses of PAN can be the major sink of PAN in regions where the temperature is low. One of these other losses is photolysis of PAN. Photolysis of PAN can produce two major products, $NO_{2}$ and $NO_{3}$. We have measured the production of $NO_{3}$ via pulsed laser photolysis with detection of $NO_{3}$ via cavity ring-down spectroscopy. Atmospheric implications of these measurements will be discussed.
Description
Author Institution: Department of Chemistry and Geophysical Institute, University of Alaska Fairbanks; Solar and Terrestrial Physics Laboratory, Nagoya University; Department of Chemistry, University of Texas at Austin