LIF SPECTROSCOPY OF JET-COOLED $CHD_{2}O$
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Date
2002
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Rotationally resolved Laser-induced Fluorescence measurement is performed on the electronic transition $\tilde{A}^{2} A^{\prime}\leftarrow \tilde{X}^{2} E_{3/2}$ of jet-cooled $CHD_{2}O$ from $2900-3100 cm^{-1}$ in vibrational excitation energy of the $\tilde{A}^{2} A^{\prime}$ state, where ab initio result suggests the fundamental of C-H stretch is located. Resorting to a rotational analysis, eight vibrational bands are recognized and characterized. The vibrational assignments are confirmed by a relative intensity analysis and the symmetries thoughtfully determined in the rotational analysis.
Description
$^{a}$Novellus Systems, Inc., 2730 Junction Ave., San Jose, CA 95134
Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University; Department of Chemistry of UC Berkeley, Chemical Sciences Division of the Lawrence Berkeley National Laboratory; Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University
Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University; Department of Chemistry of UC Berkeley, Chemical Sciences Division of the Lawrence Berkeley National Laboratory; Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University