CORRELATION OF VIBRATIONAL FREQUENCIES AND ASSIGNMENTS OF THE METHYL AMINE BORANES AND AMMONIA $BORANE^{*}$
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Date
1958
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Ohio State University
Abstract
“Ammonia borane, monomethylamine borane and dimethylamine borane, which have been synthesized quite $recently,^{1}$ lend themselves nicely to a comparative study of substances containing the boron-nitrogen dative bond. Raman spectra of these compounds together with that of trimethylamine borane have been obtained from solutions in suitable solvents. Spectra of the isotopic compounds $BD_{3}NH_{3}$, $BH_{3}ND_{3}$ and $BD_{3}ND_{3}$ have also been obtained to and in the interpretation of the results and the work has been extended to include compounds prepared with boron-10. The vibrational frequencies and assignments of this series of compounds will be discussed and in particular the frequencies associated with the boron-nitrogen dative bond.”
Description
$^{*}$This work was supported by the Wright Air Development Center of the United States Air Force under contract AF 33(616)-3343. $^{1}$S. G. Shore and R. W. Parry, J. Am. Chem. Soc. 80, 8 (1958).
Author Institution: Department of Chemistry, University of Michigan
Author Institution: Department of Chemistry, University of Michigan