TUNABLE FAR INFRARED LASER SPECTROSCOPY OF JET-COOLED CARBON CLUSTERS: THE $\nu_{2}$ BENDING VIBRATION OF $C_{3}$

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Seven rovibrational transitions of the (0110)−(0000) fundamental bending band of C3 habe been measured with high precision using a tunable far-infrared laser spectrometer. The C3 molecules were produced by laser vaporization of a graphite rod and cooled in a supersonic expansion. This is the first determination of the astronomically inportant ν2 fundamental frequency near C3 intersteller medium with far-infrared astronomy.

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Author Institution: Department of Chemistry, University of California, and Materials and chemical Sciences Division Lawrence Barkeley Laboratory

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