$^{6}Li-^{7}Li$ ISOTOPE EFFECTS IN THE $A^{1}\Sigma_{u}{^{+}}-X^{1}\Sigma_{g}{^{+}}$ BAND SYSTEM OF $Li_{2}$

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1987

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Ohio State University

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The absorption spectrum of the A-X band system of 6Li2 has been examined using a Bomem DA3.002 Fourier Transform Interferometer in the frequency range of 14200−17200cm−1. A high resolution (0.01cm−1) spectrum was measured at two different temperatures (600 and 830C) in a heat pipe overn containing helium as a buffer gas. The spectrum was analyzed to yield Dunham coefficients and Franck-Condon factors. The molecular constants calculated for 6Li2 are compared with those for 7Li2.

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Author Institution: Department of Chemistry, The Pennsylvania State University

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