THE ROTATIONAL ANALYSIS OF A-X SYSTEM OF $As_{2}$ MOLECULE.

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1969

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Ohio State University

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The rotational analysis of some five bands (6,15), (2,14), (2,15), (8,20) and (2,17) of the A-X system of As2 molecule was carried out to determine the various rotational constants. The values are comparable and more promising than those by MM. Jean D'Incan et al. The emission spectrum of As2 was photographed under high dispersion both on concave grating and plane grating spectrographs using a microwave discharge as the source of excitation. The possible electron configurations of the A1Σg+ and X1Σg+ states of As2 will be discussed.

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Author Institution: Chemistry Department, Memorial University St John's; Chemistry Department, University of Washington

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http://hdl.handle.net/1811/15824

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969