ROTATION-TRANSLATION COUPLING SPECTRUM OF MATRIX---ISOLATED MOLECULES.

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1966

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Ohio State University

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Abstract

In lattices containing molecular impurities the rotation---translation coupling effect leads to the appearance of a new type of spectral lines having the character of the constrained translational motion of the molecule. Frequencies and intensities of these lines are calculated and good agreement is obtained with observations both in the near and far infrared.

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Author Institution: The Weizmann Institute of Science

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