VIBRATIONAL SPECTRA AND ASSIGNMENTS FOR TWO FLUOROCYCLOPOPENES

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1974

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Ohio State University

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A complete assignment of vibrational fundamentals has been obtained for 1 H-trifluorocyclopropene-$d_{0}$ and -$d_{1}$. Low symmetry of the molecule has been an asset in this case. Based on normal coordinate calculations as well as spectra provisional assignments are given for 3,3-difluorocyclopropene-$d_{0}$ nd -$d_{2}$. Some generalizations concerning group frequencies in cyclopropenes will be offered.

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Author Institution: Department of Chemistry, Oberlin College

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