AN APPLICATION OF THE KEKUL\'E MODEL TO A CONDENSED AROMATIC SYSTEM: NAPHTHALENE

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1961

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Ohio State University

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An extension of the Urey-Bradley force field for aromatic rings has been applied to a calculation of the planner vibration fundamentals of naphthalene, using only sixteen force constants transferred from benzene. The results of a zero-order calculation are compared with those obtained from an unmodified UBFF and these are in turn, compared with the assignments proposed by Scully and $Whiffen^{1}$ and Freeman and $Ross.^{2}$

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$^{1}$Scully, D. B. and Whiffen, D. H., Spectrochim, Acta 16, 1409 (1961). $^{2}$Freeman, D. E. and Ross, I. G. Spectrochim, Acta 16, 1393 (1961).
Author Institution: Chemical Physics Research Laboratory, The Dow Chemical Company

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