HIGH-RESOLUTION DOUBLE-RESONANCE SPECTROSCOPY OF $\nu_{3} \rightarrow 2\nu_{3}$ TRANSITIONS IN $SF_{6}$

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1980

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Ohio State University

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Using spectroscopic constants derived from the analysis of the $3\nu_{3}$ and $SF_{6}$, we assign the double resonance diode spectra of Moulton and $Seinfeld^{2}$ and Compare their data with the calculated $2\nu_{3}$ ro-vibrational energy levels. We also calculate the vibrational multiple photon $n\nu_{3}$ ladder and describe the possible resonant pathways.

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$^{1}$P. F. Moulton, D. M. Larsen, J. N. Walpole, and A. Mooradian, Opt. Lett. 1, 51-53(1977). $^{2}$J. I. Steinfeld, Technical Progress Report, M.I.T., Cambridge Mass. 02139.
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