THE STARK-HYPERFINE SPECTRUM OF HYDROGEN FLUORIDE, $V=1$

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1984

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Ohio State University

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The J=1,M=0 to J=1,M=1 radio frequency spectrum was observed in the v=1 excited vibrational state of HF using MBER spectroscopy. The excited state was populated using a Burleigh color center IR laser to excite the beam between the source and first quadrupole field. The results include: μ=1.8737D,CF=361.2KHz,CH=−69.3 KHz, direct spin-spin=27.5 KHz, indirect spin-spin=0.42 KHz.

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Author Institution: Department of Chemistry, University of Rochester

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