THE INFRARED SPECTRUM OF $CH_{3}O$ IN THE CH STRETCHING REGION

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2004

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Ohio State University

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Since the last report,b we have made progress in obtaining and analyzing the jet-cooled high resolution spectrum of methoxy, CH3O, in the CH stretching region. Specifically, a second perpendicular band similar to the first in exhibiting Δp=+1 has been obtained and fitted. In addition two additional isolated subbands, one with perpendicular selection rules and the other with parallel selection rules have been assigned and fitted. We are attempting to achieve a global understanding of these results.

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aPresent address: Department of Chemistry, University of California, Berkeley, CA 94720. bJia-xiang Han, Yu. G. Utkin, Hong-bing Chen, L. A. Burns, and R. F. Curl, J. Chem. Phys. 117, 6538-6545 (2002).


Author Institution: Department of Chemistry, and Rice Quantum Institute, Rice University; Department of Chemistry, and Rice Quantum Institute, University of Science and Technology of China; Physical and Theoretical Chemistry Laboratory, Oxford University

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http://hdl.handle.net/1811/21536

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Abstracts of OSU International Symposium on Molecular Spectroscopy 2000-2009