CORIOLIS INTERACTION AND THE VIBRATION-ROTATION SPECTRUM OF $CClF_{3}$

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1980

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Ohio State University

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The spectrum of CClF3 has been measured at 0.1cm−1 resolution and the spacing of the Q branches in many of the perpendicular bands has been determined. From these spacings the Coriolis coefficients have been derived. These experimental values are compared with ones calculated with a Urey-Bradley force field. Of particular interest is the effect of Coriolis interaction on the band contour of combination bands involving two degenerate fundamentals.

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http://hdl.handle.net/1811/11184

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989