CORIOLIS INTERACTION AND THE VIBRATION-ROTATION SPECTRUM OF $CClF_{3}$
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Date
1980
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Ohio State University
Abstract
The spectrum of $CClF_{3}$ has been measured at $0.1 cm^{-1}$ resolution and the spacing of the Q branches in many of the perpendicular bands has been determined. From these spacings the Coriolis coefficients have been derived. These experimental values are compared with ones calculated with a Urey-Bradley force field. Of particular interest is the effect of Coriolis interaction on the band contour of combination bands involving two degenerate fundamentals.
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