MICROWAVE SPECTRA OF TRANS-1, 2-DIFLUOROETHYLENE OXIDE

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1983

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Ohio State University

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The microwave spectra of trans-1, 2-difluoroethylene oxide was investigated in the region of 26.5 to 40 GHz. A fit of the near-prolate μb-type spectrum gave the following rotational constants (MHz) for the ground state normal isotope: A=14731.47,B=3582.85 and C=3222.44. The electric dipole moment was measured to be μb=μT=1.110. The dideutero species, CDFCDFO, and the oxygen-18 species, CHFCHF180, have been assigned and presently work is in progress on the carbon-13 isotopic assignment. The isotopic data will be used to discuss the molecular structure.

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Author Institution: Department of Chemistry, Rensselaer Polytechnic Institute Troy; Department of Chemistry, Charles Stark Draper Laboratory

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