ANOMALOUS SOLUTION SPECTRA OF DIPYRRYL METHINE SALTS
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We have found the hydrobromide and hydrochloride salts of substituted dipyrryl methines to behave non-ideally in some solvents. In acetonitrile, for example, their spectra sharpened as the concentration increased with a concurrent increase in the extinctin coefficient at the peak wavelength. Maximum absorption shifted towards longer wavelength as the concentration increased. The largest changes were observed for the tetramethyl hydrobromide derivitive, where an eight-fold increase in the extinction coefficient accompanied a twenty-fold increase in concentration. These results are similar to those reported for cyanine
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