PROBING H-ATOM PRODUCTION CHANNELS IN THE FORMIC ACID DIMER
Date
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Three radical channels (HCO + OH, HCOO + H, and H + COOH) exist for the dissociation of formic acid after excitation to its first electronically excited state. We are interested in the competition between the two hydrogen channels of formic acid dimer. Partial deuteration allows for detection of either hydrogen channel. Both room temperature photoacoustic detection and jet cooled action spectra of (HCOOD)
Description
Author Institution: Department of Chemistry, University of Wisconsin-Madison, Madison, WI 53706