ABSORPTION CONTINUA OF BORON IODIDES

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1962

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Ohio State University

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The absorption spectrum of BI3 in the gaseous state showed a strong continuum in the region from A3150 to about 2500\AA. This continuum, due to the molecule BI3 is in agreement with the value extrapolated from the known known continua of the related trihalides of boron and aluminum.1 Following Schumb, Gamble, and Banus,2 the lower iodides of boron were prepared in the absorption cell by passing an electrodeless discharge through BI3 vapor. The absorption spectra of these lower iodides of boron revealed the existence of four continua in the regions λ2508−2790\AA,λ2821−2985\AA,λ3040−3203\AA, and λ3376−3585\AA. Of the continuum in the region λ3376−3585\AA is the strongest, with a maximum at λ3456\AA. and the λ3040−3203\AA continuum is the weakest. Previous work on the spectra of the diatomic halides of group III elements3 has shown that the strongest continuum can be attributed to the diatomic molecule BI. It represents a 1Π1Σ transition, with the upper 1Π state repulsive. The dissociation energy of BI is approximately 3,5 ev if in its repulsive state it dissociates to B(2P1/2) and 1(2P3/2), the lowest of the atomic states. If the molecule dissociates to B(2P1/2) and an excited I(2P1/2), then the dissociation energy is approximately 2.5 ev.

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Present address: Department of Chemistry, University of Toronto, Toronto 5. Canada. 1 R. S. Sharma, Bull. Acad. Sci. (Allahabad, India) 3, 87 (1933). S. C. Deb. Bull. Acad. Sci. (Allahabad, India) 1, 92 (1931-32). 2 W. C. Schumb, E. L. Gamble, and M. D. Banus, J. Am. Chem. Soc, 71,3225 (1949). 3 E. Miescher, Helv. Phys. Acta, 9, 693 (1936).


Author Institution: Department of Physics, Syracuse University

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