THE PURE ROTATIONAL SPECTRUM AND HYPERFINE STRUCTURE OF $HC\ell ^{+}$ STUDIED BY LASER MAGNETIC $RESONANCE^{\ast}$

Lubic, K. G.; Ray, D.; Saykally, R. J.

THE PURE ROTATIONAL SPECTRUM AND HYPERFINE STRUCTURE OF $HC\ell ^{+}$ STUDIED BY LASER MAGNETIC $RESONANCE^{\ast}$

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Date

1982

Authors

Lubic, K. G.

Ray, D.

Saykally, R. J.

Publisher

Ohio State University

Abstract

Pure rotational transitions have been measured for the $H C ℓ +$ molecular ion by the technique of far-infrared laser magnetic resonance spectroscopy. The ions were generated in an intracavity discharge through helium containing a trace of $H C ℓ$ at total pressures near 1 Torr. Measurements have been made for the $H 35 C ℓ +, H 37 C ℓ +, D 35 C ℓ +$ , and $D 37 C ℓ +$ isotopes at magnetic flux densities up to 20 kGauss. These spectra are being analyzed according to the $2 Π$ Hamiltonian of Brown.

Description

$1$ D. Ray, K.G. Lubic, and R.J. Saykally, Molec, Phys., accepted for publication. $*$ Supported by NSF Grant #CHE-8007042

URI

http://hdl.handle.net/1811/29068

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989

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