MICROWAVE SPECTRUM OF $METHYLPHOSPHINE^{*}$

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1961

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Ohio State University

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Some eighty rotational lines of the methylphosphine molecule have been measured in the region of 12-33 kmc. The rotational constants and dipole moment have been determined. The barrier to internal rotation of the methyl group, as determined from the A--E splittings of rotational lines in the ground torsional state and from the satellite frequency pattern of the $0_{00}\to 1_{01}$ transition, is $685.2\pm$$5 cm^{-1}$.

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$^{*}$Supported jointly by the National Science Foundation and Office of Naval Research.
Author Institution: Department of Physics, University of Oklahoma

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