THE $B \rightarrow X$ SYSTEM OF KrCl
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Date
1978
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The bound-free $B \rightarrow X$ (2200 {\AA}) transition In KrCl is studied as a function of the pressure of $Cl_{2}$, Kr, and several third gases (Ar, He, $N_{2}$). The infinite-pressure extrapolated spectrum is analyzed computationally to yield approximate potential curves for both states. The finite pressure data are then used to obtain relative vibrational populations for the first few v^{\prime} levels, from which we deduce quenching end vibrational relaxation rates.
Description
Author Institution: Department of Chemistry; Department of Chemistry