Knowledge Bank

It is known that the photophysical properties ofchromophores is decisively conditioned by the existence of $\pi \sigma \ast$ transitions with repulsive character, in the vicinity of the characteristic bright $\pi \pi \ast$ absorptions. The interplay between these two types of states triggers a complex dynamics that takes place in the femto-picoseconds scale., nderline{\textbf{302}}, 1693, 2003.} Our group is interested in understanding the ultrafast relaxation mechanisms involving $\pi \sigma \ast$ surfaces in a set of isolated aromatic chromofores including: aniline, indole, phenol and pyrrole. In the research carried out, the dynamical signature of the $\pi \sigma \ast$ states has been tracked directly on the parent molecules photoexcited in a broad range of their near UV absorption specta, by multiphoton delayed ionization at several wavelengths. For the studied molecules, the work provides a detailed view on the relaxation pathways available, while permits to relate their photophysical behavior with the relative location of the $\pi \sigma \ast$ and $\pi \pi \ast$ states.