$^{1}E_{1u}$ STATE OF BENZENE AND DERIVATIVES--MCD SPECTRA AND MAGNETIC MOMENTS

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1977

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Ohio State University

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The magnetic circular dichroism (MCD) spectra of the 1E1u1A1g transition of benzene and its methyl derivatives have been measured in the gas-phase and in solution. From these data, the magnetic moments of the 1E1u state in these compounds are obtained. The magnetic moments in solution decrease with increase in methyl substitution. In the gas-phase, Rydberg transitions contribute to the MCD and in some cases prevent the determination of the magnetic moment.

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Author Institution: Department of Chemistry, University of Southern California

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