MEASUREMENT OF THE VAN DER WAALS STRETCHING VIBRATION IN ArHCl BY FAR INFRARED LASER/MICROWAVE DOUBLE RESONANCE SPECTROSCOPY

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1987

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Ohio State University

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The first rotationally resolved spectrum of a van der Waals stretching vibration has been measured in the ArHCl molecular complex. Double resonance spectra have confirmed the assignment of the spectrum. The molecular constants are in good agreement with those of Hutson for a double well potential and put the band origin at $32.4 cm^{-1}$.

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$^{1}$. J.M. Huston, J. Chem. Soc. Faraday Trans. 2, B2, 1163 (1986).
Author Institution: Department of Chemistry, University of California

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http://hdl.handle.net/1811/17251

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989