THE 2.88 MICRON BAND OF FORMALDEHYDE

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1972

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Ohio State University

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Spectra of the 2ν3 band of formaldehyde have been obtained with high resolution (0.035cm−1). Measurements were made with pathlengths from 8 to 24 m and at sample pressures from 0.1 to 0.3 mm of Hg. More than 300 lines were observed and assigned for J≤21 and Ka≤9. From these data the following constants were determined in cm−1: \begin{eqnarray*} \nu_{0} = 3471.718 \pm 0.004 \ A^{\prime\prime} -A^{\prime} = 0.0117 \pm 0.0005 \ B^{\prime} = 1.28100 \pm 0.00024 \ C^{\prime} = 1.11662 \pm 0.00024 \end{eqnarray*} The line strengths of 150 observed transitions were also obtained from the data. The strengths were analyzed to determine the band strength and the rotational factors. At 296K, the strength of the 2ν3 band was found to be 15.7±0.9cm−2 atm−1. This paper presents progress of one phase of research carried out at the Jet Propulsion Laboratory, California Institute of Technology, under Contract No. NAS 7-100, Sponsored by the National Aeronautics and Space Administration.

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Author Institution: Space Sciences Division, Jet Propulsion Laboratory Pasadena

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