THE HCl/H$_2$O SOLID SYSTEM: INFRARED SPECTRA OF HCl TRI- AND HEXAHYDRATE
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Abstract
During a long time the assignment of the spectra of the various HCl hydrates, which are known to play an important role in the chemistry of the atmosphere, has been controversial (see the discussions in Refs. } and }). In this work we report a joint theoretical and experimental investigation of the vibrational spectra of the crystalline tri- and hexahydrate. The experimental measurements were carried out using grazing angle reflection-absorption IR spectroscopy (RAIRS) on HCl/H
Description
{V. Buch, J. Sadlej, N. Artemiz-Uras, J. P. Devlin, J. Phys. Chem. A 106, 9374 (2002).{I. Xueref, F. Domine, Atmosf. Chem. Phys. 3, 1779 (2003).{I. K. Ortega, R. Escribano, D. Fernandez-Torre, V. J. Herrero, B. Mate, M. A. Moreno, Chem. Phys. Lett. 396, 335 (2004).{J. M. Soler, E. Artacho, J. D. Gale, A. Garcia, J. Junquera, P. Ordejon, D. Sanchez-Portal, J. Phys. Condens. Matter 14, 2745 (2002).
Author Institution: Instituto de Estructura de la Materia (CSIC) , Serrano 123, 28006 Madrid, Spain