HIGH RESOLUTION OVERTONE SPECTROSCOPY OF ACETYLENE VAN DER WAALS COMPLEXES

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The latest upgrades and results from the FANTASIO+ set-up, \textit{Mol. Phys.} 2010, \textbf{108}, 2158-2164} (for 'Fourier trANsform, Tunable, diode and quadrupole mAss spectrometers interfaced to a Supersonic expansIOn') are presented. Thanks to the improvements of the calibration (better than ±1×10−3 cm−1 accuracy) and the ring-down time (130 μs), the spectrum of C2H2-N2 around 6500 cm−1 was recorded as well as absorption bands due to combined excitations of intra and intermolecular modes of C2H2-Ar, C2H2-CO2 and C2H2-N2O. A hot absorption band of the van der Waals complex C2H2-Ar was also observed. The first analyses of these spectra will be presented.\ \ Along the development of the FANTASIO+ set-up, a new injection system to probe samples liquid at STP conditions, and a pulse injector are currently under implementation. Those upgrades will allow the study of organic and prebiotic molecules and a better cooling of the gas in the expansion, respectively. The first results will also be presented.

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Author Institution: Service de Chimie quantique et Photophysique CP160/09, Faculte des Sciences, Universite Libre de Bruxelles (U.L.B.), Av. Roosevelt, 50, B-1050, Bruxelles, Belgium

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