RESONANT TWO-PHOTON IONIZATION TIME-OF-FLIGHT MASS SPECTROSCOPY (R2PI-TOFMS) OF JET-COOLED CuGa AND CuIn
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Date
1995
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Publisher
Ohio State University
Abstract
Diatomic CuGa and Culn produced in a low temperature molecular beam source have been studied using R2PI. For both molecules, four band systems in the $14500 to 27500 cm^{-1}$ range have been identified and analyzed. A system located in the red has been recorded at high resolution using the output of a cw ring dye laser pulse amplified using a four stage amplifier chain pumped by the second harmonic of a Nd: YAG laser. The results of this analysis, which include determinations of vibrational frequencies, bond lengths, ionization potentials and dissociation energies, will be compared with calculation using density functional theory (DFT).
Description
Author Institution: Steacie Institute For Molecular Sciences, National Research Council Canada, 100 Sussex Dr., Ottawa, On. K1A 0R6.